Facile preparation of silver nanocluster self-assemblies with aggregation-induced emission by equilibrium shifting

Abstract

Aggregation-induced emission is a promising pathway to get high photoluminescence from metal nanocluster assemblies. The self-assembly of metal nanoclusters with regular morphologies can restrict the rotation and vibration modes of capping ligands, reduce nanoclusters’ non-radiative decay, and finally result in an aggregation-induced strong emission. In this study, silver nanocluster self-assemblies stabilized by thiosalicylic acid (TSA) were prepared in water by equilibrium shifting, which exhibit nanofiber-like morphologies. The resulting silver nanocluster self-assemblies exhibit aggregation-induced emission in solid or aggregated state with a decent quantum yield i.e., 13.05%. The obtained silver nanocluster self-assemblies were thoroughly characterized by fluorescence spectroscopy, UV-visible absorption spectroscopy, X-ray photoelectron spectroscopy (XPS), matrix assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI-TOF), powder X-ray diffraction (PXRD) and high-resolution transmission electron microscopy (HRTEM). These silver nanocluster self-assemblies with high photoluminescence in aggregated state may have potential use in light emitting devices and bioapplications.