Cost and energy efficient cyclic separation of 5-hydroxymethyl furfural from an aqueous solution

Abstract

The efficient separation of 5-hydroxymethyl furfural (HMF) – a platform chemical in biomass valorization – from the reactive aqueous mixture of sugars is key to improving its economic production. Here we demonstrate a cyclic fixed-bed process that selectively adsorbs HMF from the aqueous phase, purifies the solute, and enables its subsequent desorption in a suitable solvent for downstream applications. This intensified process bypasses the traditional energy-intensive recovery of HMF via vacuum distillation. The adsorption and desorption performances of a commercially available polymer-based spherical activated carbon (PBSAC) are quantified in batch and continuous systems. The effects of temperature (25–90 °C) and co-existence of other components from the fructose dehydration reaction (fructose, formic acid, and levulinic acid) on adsorption are evaluated. Model predictions based on parameters extracted from batch isotherms describe reasonably the continuous experimental breakthrough curve with suitable transport parameters. It is demonstrated that HMF can be selectively purified and recovered, and the adsorption column can be reused for at least seven cycles tested here. A simple analysis further showcases nearly tenfold cost and energy savings for HMF separation. The framework outlined here can be applied to other biomass solutes.