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C(sp3)–H Bond Functionalization with Styrenes via Hydrogen-Atom Transfer to an Aqueous Hydroxyl Radical under Photocatalysis

Shogo Mori  and  Susumu Saito  

Abstract

The redox-neutral addition of α-C–H bonds of acetonitrile and acetone to styrenes was enabled via the hydrogen-atom transfer from relatively acidic and water-miscible C(sp3)–H bonds to an aqueous hydroxyl radical generated cleanly and iteratively by the oxidation of water under silver-nanoparticle-loaded titania photocatalysis without using stoichiometric oxidation agents.

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Article information

https://doi.org/10.1039/D1GC00753J
Submitted
28 Feb 2021
Accepted
07 Apr 2021
First published
07 Apr 2021
Green Chem., 2021, Accepted Manuscript
Article type
Communication
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C(sp3)–H Bond Functionalization with Styrenes via Hydrogen-Atom Transfer to an Aqueous Hydroxyl Radical under Photocatalysis

S. Mori and S. Saito, Green Chem., 2021, Accepted Manuscript , DOI: 10.1039/D1GC00753J

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