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Issue 1, 2021
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Electro-oxidative C–H alkylation of quinoxalin-2(1H)-ones with organoboron compounds

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Abstract

Radical cleavage of C–B bonds to accomplish C–H functionalization is synthetically appealing but practically challenging. We report herein a mild electro-oxidative method for efficient C–H alkylation of quinoxalin-2(1H)-ones by means of radical addition reactions of alkyl boronic acids and esters and alkyl trifluoroborates to afford C–C coupled products.

Graphical abstract: Electro-oxidative C–H alkylation of quinoxalin-2(1H)-ones with organoboron compounds

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Article information


Submitted
17 Nov 2020
Accepted
15 Dec 2020
First published
15 Dec 2020

Green Chem., 2021,23, 302-306
Article type
Communication

Electro-oxidative C–H alkylation of quinoxalin-2(1H)-ones with organoboron compounds

K. Niu, Y. Hao, L. Song, Y. Liu and Q. Wang, Green Chem., 2021, 23, 302
DOI: 10.1039/D0GC03892J

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