Synthesis of an expanded pincer ligand and its bimetallic coinage metal complexes

Abstract

An expanded pincer ligand tBu-PONNOP (2,7-bis(di-tert-butylphosphinito)-1,8-naphthyridine) has been synthesised and its coordination to coinage metals has been studied. Bimetallic complexes were produced with metal halide salts of the type [M₂X₂(tBu-PONNOP)] (X = Cl, M = Au, Ag, Cu; X = I, M = Cu) with a varying degree of interaction with the naphthyridyl backbone in the order Au < Ag < Cu. The salts [Ag₂(tBu-PONNOP)₂][BAr^F₄]₂ (Ar^F = 3,5-C₆H₃(CF₃)₂) and [Ag₂(NCMe)₂(tBu-PONNOP)]X₂ (X = BAr^F₄, PF₆) were prepared, which may serve as a source of tBu-PONNOP via transmetallation.