Dinuclear triple stranded phenyl-spaced 1,3-bis-β-diketonato lanthanide(iii) complexes: synthesis, structures and spectroscopy

Abstract

The synthesis and crystal structures of a series of Ln(III) (Ln = Gd, Nd, Yb as well as Y) complexes of a bis-β-diketone ligand incorporating a 1,3-substituted phenyl ring between its two β-diketone domains (1,1′-(1,3-phenylene)bis(4,4-dimethylpentane-1,3-dione), H₂L¹) is reported. The crystal structures show the complexes are seven coordinate in the solid state with the general formula [Ln₂L¹₃(solvent)₂]. The photophysical properties of the complexes were explored in both solution and the solid state, which show an increase in coordination number in solution.