Issue 2, 2021

Magnetism in a helicate complexes arising with the tetradentate ligand

Abstract

The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1–3, show intermolecular π–π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

Graphical abstract: Magnetism in a helicate complexes arising with the tetradentate ligand

Supplementary files

Article information

Article type
Communication
Submitted
21 Nov 2020
Accepted
15 Dec 2020
First published
18 Dec 2020

Dalton Trans., 2021,50, 494-498

Magnetism in a helicate complexes arising with the tetradentate ligand

H. Ohmagari, M. Nakaya, K. Tanaka, H. Zenno, R. Akiyoshi, Y. Sekine, Y. Zhang, K. S. Min, M. Hasegawa, L. F. Lindoy and S. Hayami, Dalton Trans., 2021, 50, 494 DOI: 10.1039/D0DT03990J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements