Comparison of the catalytic performance of Au/TiO2 prepared by in situ photodeposition and deposition precipitation methods for CO oxidation at room temperature under visible light irradiation

Abstract

A Au/TiO₂-PD sample was prepared via a mild in situ photodeposition method followed by heat treatment. As compared to Au/TiO₂-DP prepared by deposition precipitation, this Au/TiO₂-PD sample owned the smaller sizes of Au nanoparticles (Au NPs), and exhibited a better catalytic activity for CO oxidation under visible light irradiation or otherwise. The results of XPS, in situ EPR and in situ DRIFTS tests indicated that TiO₂ could transfer electrons to Au NPs caused the increase in surface electron density of Au NPs, resulting in the enhanced adsorption of CO at Au sites. This adsorbed CO could interact with the lattice O of TiO₂ to form CO₂ accompanied by oxygen vacancy, while O₂ could be adsorbed at the oxygen vacancy to form the lattice O of TiO₂ again. Moreover, the other oxygen atom of O₂ adsorbed at oxygen vacancy may form activated O⁻ species at adjacent Au sites, which can further react with another CO adsorbed at Au sites to form CO₂. As compared with Au/TiO₂-DP, the Au/TiO₂-PD sample showed more electron transfer from TiO₂ to Au sites (meaning more CO activation) and then the more activation of O₂, resulting in an ultra-high activity of CO oxidation. Further, under visible light, the Au/TiO₂-PD sample also exhibited a more obvious photopromoted effect due to the higher surface electron density of Au NPs induced by LSPR effect than Au/TiO₂-DP. This study showed that the effect of Au NPs size on CO oxidation may somewhat be attributed to the electron transfer behavior.