Intrinsic chemistry of [OUCH]+: reactions with H2O, CH3CN and O2

Luke J. Metzler; Christopher T. Farmen; Theodore A. Corcovilos; Michael J. Van Stipdonk

doi:10.1039/D1CP00177A

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Intrinsic chemistry of [OUCH]⁺: reactions with H₂O, CH₃CN and O₂†

Luke J. Metzler,

^a Christopher T. Farmen,^a Theodore A. Corcovilos

^b and Michael J. Van Stipdonk

*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, Duquesne University, 600 Forbes Ave., Pittsburgh, PA 15282, USA
E-mail: vanstipdonkm@duq.edu

^b Department of Physics, Duquesne University, 600 Forbes Ave., Pittsburgh, PA 15282, USA

Abstract

We report the first experimental study of the intrinsic chemistry of a U-methylidyne species, focusing on reaction of [OUCH]⁺ with H₂O, O₂ and CH₃C [triple bond, length as m-dash] N in the gas phase. DFT was also used to determine reaction pathways, and establish the mechanism by which [OUCH]⁺ is formed through collision-induced dissociation of [UO₂(CCH)]⁺.

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Article information

DOI: https://doi.org/10.1039/D1CP00177A
Article type: Communication
Submitted: 13 Jan 2021
Accepted: 11 Feb 2021
First published: 11 Feb 2021

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Phys. Chem. Chem. Phys., 2021,23, 4475-4479

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Intrinsic chemistry of [OUCH]⁺: reactions with H₂O, CH₃CN and O₂

L. J. Metzler, C. T. Farmen, T. A. Corcovilos and M. J. Van Stipdonk, Phys. Chem. Chem. Phys., 2021, 23, 4475 DOI: 10.1039/D1CP00177A

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