Issue 33, 2021

The effect of a micro-crystalline ZnO with columnar structure on the crystallization behavior and mechanical properties of poly(ethylene 2,6-naphthalate)

Abstract

In this study, we synthesized a type of microcrystalline H-ZnOc with columnar structure by controlling the solubility of the reaction solution. Poly(ethylene 2,6-naphthalate) (PEN) and hexagonal zinc oxide column (H-ZnOc) composite materials were prepared by a twin screw extruder and the properties of the composites were characterized. The results showed that H-ZnOc has a remarkable nucleation effect on PEN, especially when the loading amount of H-ZnOc is 1.5 wt%; the nucleation efficiency is as high as 52.28%, and the crystallization temperature increased by nearly 23 °C. The crystal morphology changed, with the disappearance of the cold crystallization peak after the addition of H-ZnOc, the size of spherulites decreased and the number of spherulites increased. During the isothermal crystallization process, H-ZnOc significantly reduced the crystallization time of PEN. The impact strength of PEN increased from 1.86 kJ m−2 to 2.73 kJ m−2. Our results showed that H-ZnOc can be used as an effective nucleating agent for PEN, effectively improving the crystallization ability and mechanical properties, and its performance is comparable to the proprietary polymer nucleating agents NX8000, HPN68L, and TMB-5, etc.

Graphical abstract: The effect of a micro-crystalline ZnO with columnar structure on the crystallization behavior and mechanical properties of poly(ethylene 2,6-naphthalate)

Supplementary files

Article information

Article type
Paper
Submitted
11 May 2021
Accepted
14 Jul 2021
First published
17 Jul 2021

CrystEngComm, 2021,23, 5655-5662

The effect of a micro-crystalline ZnO with columnar structure on the crystallization behavior and mechanical properties of poly(ethylene 2,6-naphthalate)

J. Yao, X. Li, J. Lu, Q. Ma, Y. Liu and F. Luo, CrystEngComm, 2021, 23, 5655 DOI: 10.1039/D1CE00629K

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