Issue 96, 2021
From the journal:

Chemical Communications

Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol†

Michal Aman,a   Libor Dostál, ORCID logo a   Aleš Růžička, ORCID logo a   Jiří Tydlitát,a   Jens Beckmann, ORCID logo b   Jan Turek ORCID logo *c  and  Roman Jambor ORCID logo *a  

* Corresponding authors

a Department of General and Inorganic Chemistry, University of Pardubice, 532 10 Pardubice, Czech Republic
E-mail: roman.jambor@upce.cz

b Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359 Bremen, Germany

c Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium
E-mail: jan.turek@vub.be

Abstract

A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(III) complex or as a κ2Sn,P-chelating ligand for Ru(II) compounds.

Graphical abstract: Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

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Article information

DOI
https://doi.org/10.1039/D1CC06173A
Article type
Communication
Submitted
02 Nov 2021
Accepted
15 Nov 2021
First published
15 Nov 2021

Chem. Commun., 2021,57, 12992-12995

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Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

M. Aman, L. Dostál, A. Růžička, J. Tydlitát, J. Beckmann, J. Turek and R. Jambor, Chem. Commun., 2021, 57, 12992 DOI: 10.1039/D1CC06173A

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