Electrochemical hydrogen formation catalysed by a Pd8 string

Tomoaki Tanase; Kanako Nakamae; Haruka Miyano; Yoshimi Fujisawa; Yasuyuki Ura; Takayuki Nakajima

doi:10.1039/D1CC04788D

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Electrochemical hydrogen formation catalysed by a Pd₈ string†

Tomoaki Tanase,

*^a Kanako Nakamae,^a Haruka Miyano,^a Yoshimi Fujisawa,^a Yasuyuki Ura

^a and Takayuki Nakajima

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-nishi-machi, Nara 630-8506, Japan
E-mail: tanase@cc.nara-wu.ac.jp

Abstract

The linear Pd₈ complex supported by tetraphosphines reacted with HBF₄ to give an unprecedented linear tetrapalladium complex with a terminal hydride, which promoted electrocatalytic hydrogen formation from HBF₄ in acetonitrile. The 1D coordination polymer of Pd₈ chain confined within Nafion film was applied to the electrocatalytic H₂ formation.

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Article information

DOI: https://doi.org/10.1039/D1CC04788D
Article type: Communication
Submitted: 27 Aug 2021
Accepted: 06 Oct 2021
First published: 06 Oct 2021

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Chem. Commun., 2021,57, 11264-11267

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Electrochemical hydrogen formation catalysed by a Pd₈ string

T. Tanase, K. Nakamae, H. Miyano, Y. Fujisawa, Y. Ura and T. Nakajima, Chem. Commun., 2021, 57, 11264 DOI: 10.1039/D1CC04788D

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Chemical Communications