Insights into carbon nanotube-assisted electro-oxidation of polycyclic aromatic hydrocarbons for mediated bioelectrocatalysis†
Paulo Henrique M.
Buzzetti, 
ab
Pierre-Yves
Blanchard,
‡a
Yuta
Nishina,
c
Serge
Cosnier,
a
Alan
Le Goff
*a
and
Michael
Holzinger
*a
ab
Pierre-Yves
Blanchard,
‡a
Yuta
Nishina,
c
Serge
Cosnier,
a
Alan
Le Goff
*a
and
Michael
Holzinger
*a
Abstract
A series of polycyclic aromatics, naphthalene, phenanthrene, perylene, pyrene, 1-pyrenebutyric acid N-hydroxysuccinimide ester (pyrene NHS) and coronene, were immobilized via π stacking on carbon nanotube (CNT) electrodes and electro-oxidized in aqueous solutions. The obtained quinones were characterized and evaluated for the mediated electron transfer with FAD dependent glucose dehydrogenase during catalytic glucose oxidation.
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