Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions

Marjan Hosseinzadeh; Sergio Sanz; Jan van Leusen; Natalya V. Izarova; Euan K. Brechin; Scott J. Dalgarno; Paul Kögerler

doi:10.1039/D1CC02910J

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Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions†

Marjan Hosseinzadeh,

‡*^a Sergio Sanz,

‡^bc Jan van Leusen,

^a Natalya V. Izarova,

^ab Euan K. Brechin,

*^d Scott J. Dalgarno

*^e and Paul Kögerler

*^abc

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, Aachen 52056, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de, marjan.hosseinzadeh@ac.rwth-aachen.de

^b Peter Grünberg Institute, Electronic Properties (PGI-6), Forschungszentrum Jülich, Jülich 52425, Germany

^c Jülich-Aachen Research Alliance, Fundamentals for Future Information Technology (JARA-FIT), Forschungszentrum Jülich, Jülich 52425, Germany

^d EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, UK
E-mail: ebrechin@ed.ac.uk

^e Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, UK
E-mail: S.J.Dalgarno@hw.ac.uk

Abstract

Combination of phosphoryl and calix[4]arene moieties in the same organic framework (L_PO) directs the formation of homoleptic double–decker complexes [Ln^III(L_PO)₂](OTf)₃ for Ln = Tb and Dy, with the latter displaying slow relaxation of the magnetisation.

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DOI: https://doi.org/10.1039/D1CC02910J
Article type: Communication
Submitted: 02 Jun 2021
Accepted: 19 Jul 2021
First published: 20 Jul 2021

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Chem. Commun., 2021,57, 8087-8090

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Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions

M. Hosseinzadeh, S. Sanz, J. van Leusen, N. V. Izarova, E. K. Brechin, S. J. Dalgarno and P. Kögerler, Chem. Commun., 2021, 57, 8087 DOI: 10.1039/D1CC02910J

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Chemical Communications

Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions†

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