Issue 60, 2021
From the journal:

Chemical Communications

Vinylboronic acid pinacol ester as a vinyl alcohol-precursor monomer in radical copolymerization with styrene†

Hiroshi Makino,a   Tsuyoshi Nishikawa ORCID logo *a  and  Makoto Ouchi ORCID logo *a  

* Corresponding authors

a Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: nishikawa.tsuyoshi.8n@kyoto-u.ac.jp, ouchi.makoto.2v@kyoto-u.ac.jp

Abstract

The use of vinylboronic acid pinacol ester (VBpin) as a comonomer and post-polymerization oxidation afforded vinyl alcohol (VA)–styrene copolymers, which were difficult to synthesize using a typical VA precursor monomer, vinyl acetate (VAc). The molar mass was controllable by applying RAFT polymerization and the VA composition ratio could be tuned from 11% to 72%. The solubility and glass-transition temperature were also evaluated with the copolymers of different composition ratios.

Graphical abstract: Vinylboronic acid pinacol ester as a vinyl alcohol-precursor monomer in radical copolymerization with styrene

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Article information

DOI
https://doi.org/10.1039/D1CC02603H
Article type
Communication
Submitted
18 May 2021
Accepted
30 Jun 2021
First published
30 Jun 2021

Chem. Commun., 2021,57, 7410-7413

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Vinylboronic acid pinacol ester as a vinyl alcohol-precursor monomer in radical copolymerization with styrene

H. Makino, T. Nishikawa and M. Ouchi, Chem. Commun., 2021, 57, 7410 DOI: 10.1039/D1CC02603H

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