Issue 49, 2021

Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

Abstract

Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.

Graphical abstract: Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

Supplementary files

Article information

Article type
Communication
Submitted
23 Apr 2021
Accepted
13 May 2021
First published
13 May 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 5999-6002

Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

T. Kawasaki, Y. Kaimori, S. Shimada, N. Hara, S. Sato, K. Suzuki, T. Asahi, A. Matsumoto and K. Soai, Chem. Commun., 2021, 57, 5999 DOI: 10.1039/D1CC02162A

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