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A cage-opened C60 derivative was found to undergo an unusual annulative orifice-closure reaction under high-pressure conditions, in which the orifice size changed from a 16- to a 13-membered ring. The structure was different from that obtained by the reaction at 1 atm. The theoretical calculations suggested that the formation of the former one is thermodynamically favored.
Y. Hashikawa, K. Kizaki and Y. Murata, Chem. Commun., 2021, 57, 5322 DOI: 10.1039/D1CC01662H
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