Issue 48, 2021

High-temperature electron transfer coupled spin transition (ETCST) with hysteresis in a discrete [Fe2Co2] Prussian blue analogue

Abstract

A thermoresponsive Fe–Co based discrete Prussian blue analogue (PBA) with the general formula [Fe(Tp)(CN)3]2[Co{en(Bn)py}]2(ClO4)2·4MeOH·4H2O i.e. [1·4MeOH·4H2O] is reported, which discloses a sharp and high temperature ETCST along with a wide hysteresis of 10 K observed for its desolvated complex 1.

Graphical abstract: High-temperature electron transfer coupled spin transition (ETCST) with hysteresis in a discrete [Fe2Co2] Prussian blue analogue

Supplementary files

Article information

Article type
Communication
Submitted
03 Mar 2021
Accepted
12 May 2021
First published
12 May 2021

Chem. Commun., 2021,57, 5925-5928

High-temperature electron transfer coupled spin transition (ETCST) with hysteresis in a discrete [Fe2Co2] Prussian blue analogue

J. Yadav, D. J. Mondal and S. Konar, Chem. Commun., 2021, 57, 5925 DOI: 10.1039/D1CC01160J

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