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Issue 39, 2021
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Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3]

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Abstract

We present the synthesis and characterization of the first non-classical Cl(I) polyinterhalide [NMe4][F(ClF)3] as well as the homologous polychloride [NPr3Me][Cl7]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl2, respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)3] anion.

Graphical abstract: Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3]−

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Article information


Submitted
26 Feb 2021
Accepted
07 Apr 2021
First published
07 Apr 2021

This article is Open Access

Chem. Commun., 2021,57, 4843-4846
Article type
Communication

Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3]

P. Pröhm, N. Schwarze, C. Müller, S. Steinhauer, H. Beckers, S. M. Rupf and S. Riedel, Chem. Commun., 2021, 57, 4843
DOI: 10.1039/D1CC01088C

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