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Issue 38, 2021
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Wireless electrochemiluminescence at functionalised gold microparticles using 3D titanium electrode arrays

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Abstract

Wireless electrochemiluminescence is generated using interdigitated, 3D printed, titanium arrays as feeder electrodes to shape the electric field. Gold microparticles (45 μm diameter), functionalised with 11-mercaptoundecanoic acid, act as micro-emitters to generate electrochemiluminescence from [Ru(bpy)3]2+, (bpy is 2,2′-bipyridine) where the co-reactant is tripropylamine. The oxide coated titanium allows intense electric fields, whose distribution depends on the geometry of the array, to be created in the absence of deliberately added electrolyte. COMSOL modelling and long exposure ECL imaging have been used to map the electric field distribution. Significantly, we demonstrate that by controlling the surface charge of the gold microparticles through the solution pH, the light intensity can be increased by a factor of more than 10.

Graphical abstract: Wireless electrochemiluminescence at functionalised gold microparticles using 3D titanium electrode arrays

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Supplementary files

Article information


Submitted
22 Feb 2021
Accepted
09 Apr 2021
First published
15 Apr 2021

Chem. Commun., 2021,57, 4642-4645
Article type
Communication

Wireless electrochemiluminescence at functionalised gold microparticles using 3D titanium electrode arrays

S. F. Douman, D. Collins, L. R. Cumba, S. Beirne, G. G. Wallace, Z. Yue, E. I. Iwuoha, F. Melinato, Y. Pellegrin and R. J. Forster, Chem. Commun., 2021, 57, 4642
DOI: 10.1039/D1CC01010G

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