Issue 29, 2021
From the journal:

Chemical Communications

A phosphonium ylide as a visible light organophotoredox catalyst†

Yasunori Toda, ORCID logo *a   Katsumi Tanaka,b   Riki Matsuda,b   Tomoyuki Sakamoto,b   Shiho Katsumi, ORCID logo b   Masahiro Shimizu, ORCID logo a   Fuyuki Ito ORCID logo *c  and  Hiroyuki Suga ORCID logo *a  

* Corresponding authors

a Department of Materials Chemistry, Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan
E-mail: ytoda@shinshu-u.ac.jp

b Graduate School of Science and Technology, Shinshu University, Japan

c Department of Chemistry, Institute of Education, Shinshu University, 6-ro, Nishinagano, Nagano, Japan

Abstract

A phosphonium ylide-based visible light organophotoredox catalyst has been designed and successfully applied to halohydrin synthesis using trichloroacetonitrile and epoxides. An oxidative quenching cycle by the ylide catalyst was established, which was confirmed by experimental mechanistic studies.

Graphical abstract: A phosphonium ylide as a visible light organophotoredox catalyst

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Article information

DOI
https://doi.org/10.1039/D1CC00996F
Article type
Communication
Submitted
22 Feb 2021
Accepted
08 Mar 2021
First published
08 Mar 2021

Chem. Commun., 2021,57, 3591-3594

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A phosphonium ylide as a visible light organophotoredox catalyst

Y. Toda, K. Tanaka, R. Matsuda, T. Sakamoto, S. Katsumi, M. Shimizu, F. Ito and H. Suga, Chem. Commun., 2021, 57, 3591 DOI: 10.1039/D1CC00996F

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