Issue 31, 2021
From the journal:

Chemical Communications

Heterogeneously Ni–Pd nanoparticle-catalyzed base-free formal C–S bond metathesis of thiols†

Kanju Mitamura,a   Takafumi Yatabe, ORCID logo *a   Kidai Yamamoto,a   Tomohiro Yabe, ORCID logo a   Kosuke Suzuki ORCID logo a  and  Kazuya Yamaguchi ORCID logo *a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: kyama@appchem.t.u-tokyo.ac.jp, yatabe@appchem.t.u-tokyo.ac.jp
Fax: +81-3-5841-7220

Abstract

This study rationally designed a heterogeneously catalyzed system (i.e., using Ni–Pd alloy nanoparticles supported on hydroxyapatite (Ni–Pd/HAP) under an H2 atmosphere) achieving an efficient base-free formal C–S bond metathesis of various thiols via suppression of the Ni catalysis deactivation.

Graphical abstract: Heterogeneously Ni–Pd nanoparticle-catalyzed base-free formal C–S bond metathesis of thiols

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Article information

DOI
https://doi.org/10.1039/D1CC00995H
Article type
Communication
Submitted
22 Feb 2021
Accepted
22 Mar 2021
First published
22 Mar 2021

Chem. Commun., 2021,57, 3749-3752

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Heterogeneously Ni–Pd nanoparticle-catalyzed base-free formal C–S bond metathesis of thiols

K. Mitamura, T. Yatabe, K. Yamamoto, T. Yabe, K. Suzuki and K. Yamaguchi, Chem. Commun., 2021, 57, 3749 DOI: 10.1039/D1CC00995H

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