Issue 37, 2021
From the journal:

Chemical Communications

Chain-capper effect to bias the amplification of asymmetry in supramolecular polymers†

Cristina Naranjo, ORCID logo a   Yeray Dorca, ORCID logo a   Goutam Ghosh, ORCID logo b   Rafael Gómez,a   Gustavo Fernández*b  and  Luis Sánchez ORCID logo *a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias Químicas, Complutense de Madrid, Ciudad Universitaria, s/n, Madrid, Spain
E-mail: lusamar@ucm.es

b Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 36, 48149 Münster, Germany
E-mail: fernandg@uni-muenster.de

Abstract

The kinetically controlled amplification of asymmetry experienced in the co-assembly of chiral tribiphenylaminetricarboxamides (S)-1 and (R)-1 is investigated. The formation of metastable monomeric species through intramolecular H-bonds retards the efficient amplification of asymmetry due to a chain-capper effect.

Graphical abstract: Chain-capper effect to bias the amplification of asymmetry in supramolecular polymers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CC00740H
Article type
Communication
Submitted
08 Feb 2021
Accepted
30 Mar 2021
First published
30 Mar 2021

Chem. Commun., 2021,57, 4500-4503

Permissions

Request permissions

Chain-capper effect to bias the amplification of asymmetry in supramolecular polymers

C. Naranjo, Y. Dorca, G. Ghosh, R. Gómez, G. Fernández and L. Sánchez, Chem. Commun., 2021, 57, 4500 DOI: 10.1039/D1CC00740H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements