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Issue 26, 2021
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Interconversion between a silaimine and an aminosilylene supported by an iminophosphonamide ligand

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Abstract

The reaction of a chlorosilylene, supported by an iminophosphonamide ligand, with KN(SiMe3)2 resulted in the formation of a silaimine instead of the expected aminosilylene. However, this silaimine exists in equilibrium with the corresponding aminosilylene, which was experimentally demonstrated using variable-temperature NMR spectroscopy and a trapping reaction with elemental selenium to give a silaselenourea.

Graphical abstract: Interconversion between a silaimine and an aminosilylene supported by an iminophosphonamide ligand

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Article information


Submitted
04 Feb 2021
Accepted
01 Mar 2021
First published
02 Mar 2021

Chem. Commun., 2021,57, 3203-3206
Article type
Communication

Interconversion between a silaimine and an aminosilylene supported by an iminophosphonamide ligand

S. Takahashi, A. Ishii and N. Nakata, Chem. Commun., 2021, 57, 3203
DOI: 10.1039/D1CC00667C

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