Diverse diaryl sulfide synthesis through consecutive aryne reactions

Hana Nakajima; Yuki Hazama; Yuki Sakata; Keisuke Uchida; Takamitsu Hosoya; Suguru Yoshida

doi:10.1039/D0CC08373A

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Diverse diaryl sulfide synthesis through consecutive aryne reactions†

Hana Nakajima,^a Yuki Hazama,^a Yuki Sakata,^a Keisuke Uchida,^a Takamitsu Hosoya

^a and Suguru Yoshida

*^a

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* Corresponding authors

^a Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University (TMDU), 2-3-10 Kanda-Surugadai, Chiyoda-ku, Japan
E-mail: s-yoshida.cb@tmd.ac.jp

Abstract

An efficient method to synthesize diaryl sulfides with structural diversity is disclosed. Demethylative hydrothiolation of aryne intermediates generated from o-iodoaryl triflates with methylthio-substituted o-silylaryl triflates and further aryne reactions afford diverse diaryl sulfides.

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Article information

DOI: https://doi.org/10.1039/D0CC08373A
Article type: Communication
Submitted: 28 Dec 2020
Accepted: 01 Feb 2021
First published: 01 Feb 2021

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Chem. Commun., 2021,57, 2621-2624

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Diverse diaryl sulfide synthesis through consecutive aryne reactions

H. Nakajima, Y. Hazama, Y. Sakata, K. Uchida, T. Hosoya and S. Yoshida, Chem. Commun., 2021, 57, 2621 DOI: 10.1039/D0CC08373A

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Chemical Communications

Diverse diaryl sulfide synthesis through consecutive aryne reactions†

Abstract

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Article information

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Diverse diaryl sulfide synthesis through consecutive aryne reactions

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