Heteroternary cucurbit[8]uril complexes as supramolecular scaffolds for self-assembled bifunctional photoredoxcatalysts

Fabian Lutz; Nerea Lorenzo-Parodi; Torsten C. Schmidt; Jochen Niemeyer

doi:10.1039/D0CC08025J

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Heteroternary cucurbit[8]uril complexes as supramolecular scaffolds for self-assembled bifunctional photoredoxcatalysts†‡

Fabian Lutz,^a Nerea Lorenzo-Parodi,^b Torsten C. Schmidt

^b and Jochen Niemeyer

*^a

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* Corresponding authors

^a Faculty of Chemistry, Organic Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstrasse. 7, Essen 45141, Germany
E-mail: jochen.niemeyer@uni-due.de

^b Instrumental Analytical Chemistry and Centre for Water and Environmental Research (ZWU), Universitätsstrasse 5, Essen 45141, Germany

Abstract

The self-assembly of bifunctional photoredoxcatalysts is reported. A series of photosensitizers and water-reducing catalysts were functionalized with viologen- and naphthol-units, respectively. Subsequent formation of the heteroternary cucurbit[8]uril-viologen–naphthol complexes was used for the constitution of bifunctional photoredoxcatalysts for hydrogen generation.

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Article information

DOI: https://doi.org/10.1039/D0CC08025J
Article type: Communication
Submitted: 10 Dec 2020
Accepted: 04 Feb 2021
First published: 04 Feb 2021
This article is Open Access

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Chem. Commun., 2021,57, 2887-2890

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Heteroternary cucurbit[8]uril complexes as supramolecular scaffolds for self-assembled bifunctional photoredoxcatalysts

F. Lutz, N. Lorenzo-Parodi, T. C. Schmidt and J. Niemeyer, Chem. Commun., 2021, 57, 2887 DOI: 10.1039/D0CC08025J

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Chemical Communications

Heteroternary cucurbit[8]uril complexes as supramolecular scaffolds for self-assembled bifunctional photoredoxcatalysts†‡

Abstract

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Heteroternary cucurbit[8]uril complexes as supramolecular scaffolds for self-assembled bifunctional photoredoxcatalysts

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