The direct, graft-through, ring-opening metathesis polymerisation (ROMP) of unprotected DNA macromonomers is reported. By tuning the polymerisation conditions, good control is achieved, enabling the rapid and efficient synthesis of DNA-containing bottlebrush copolymers, without the need for protection of the DNA bases.
L. A. Arkinstall, J. T. Husband, T. R. Wilks, J. C. Foster and R. K. O'Reilly, Chem. Commun., 2021, 57, 5466 DOI: 10.1039/D0CC08008J
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