Constructing an unprecedented {MnII38} matryoshka doll with a [Mn18(CO3)9] inorganic core and magnetocaloric effect

Tai-Xue Wu; Ye Tao; Qiu-Ju He; Hai-Ye Li; He-Dong Bian; Fu-Ping Huang

doi:10.1039/D0CC07884K

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Constructing an unprecedented {Mn^II₃₈} matryoshka doll with a [Mn₁₈(CO₃)₉] inorganic core and magnetocaloric effect†

Tai-Xue Wu,^a Ye Tao,^a Qiu-Ju He,^a Hai-Ye Li,*^a He-Dong Bian

^a and Fu-Ping Huang

*^a

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* Corresponding authors

^a State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, P. R. China
E-mail: lihaiye2010@163.com, huangfp2010@163.com
Fax: +86-773-2120958

Abstract

An unprecedented inner [Mn₁₈(CO₃)₉] inorganic core and [Mn₂₀] metal–organic periphery compose a high-nuclearity homometallic single-valent {Mn^II₃₈} molecular aggregate with a [Mn₆] ⊂ [Mn₁₂] ⊂ [Mn₈] ⊂ [Mn₁₂] matryoshka doll-like skeleton that displays a significant magnetocaloric effect (MCE).

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Article information

DOI: https://doi.org/10.1039/D0CC07884K
Article type: Communication
Submitted: 03 Dec 2020
Accepted: 15 Feb 2021
First published: 16 Feb 2021

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Chem. Commun., 2021,57, 2732-2735

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Constructing an unprecedented {Mn^II₃₈} matryoshka doll with a [Mn₁₈(CO₃)₉] inorganic core and magnetocaloric effect

T. Wu, Y. Tao, Q. He, H. Li, H. Bian and F. Huang, Chem. Commun., 2021, 57, 2732 DOI: 10.1039/D0CC07884K

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