Issue 9, 2021
From the journal:

Chemical Communications

A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione†

Kilingaru I. Shivakumar, ORCID logo a   Shin-ichiro Noro, ORCID logo b   Yuna Yamaguchi,c   Yusuke Ishigaki, ORCID logo d   Akinori Saeki, ORCID logo e   Kiyonori Takahashi, ORCID logo a   Takayoshi Nakamura*a  and  Ichiro Hisaki ORCID logo *c  

* Corresponding authors

a Research Institute for Electronic Science, Hokkaido University, Sapporo, Hokkaido 001-0020, Japan
E-mail: tnaka@es.hokudai.ac.jp

b Faculty of Environmental Earth Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan

c Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
E-mail: hisaki@chem.es.osaka-u.ac.jp

d Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan

e Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, Japan

Abstract

Redox-active hexakis(4-carboxyphenyl) tri(dithiolylidene)cyclohexanetrione (CPDC) was synthesized. The CPDC-based porous framework, constructed via anomalistic helical hydrogen-bonding, exhibites permanent porosity and photoconductivity.

Graphical abstract: A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione

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Article information

DOI
https://doi.org/10.1039/D0CC07776C
Article type
Communication
Submitted
27 Nov 2020
Accepted
17 Dec 2020
First published
17 Dec 2020

Chem. Commun., 2021,57, 1157-1160

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A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione

K. I. Shivakumar, S. Noro, Y. Yamaguchi, Y. Ishigaki, A. Saeki, K. Takahashi, T. Nakamura and I. Hisaki, Chem. Commun., 2021, 57, 1157 DOI: 10.1039/D0CC07776C

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