Issue 8, 2021

Aryl-substituted triarsiranes: synthesis and reactivity

Abstract

Cyclotriarsanes are rare and described herein is a scalable synthetic protocol towards (AsAr)3, which allowed to study their reactivity towards [Cp2Ti(C2(SiMe3)2)], affording titanocene diarsene complexes, and towards N-heterocyclic carbenes (NHCs) to give straightforward access to a variety of NHC-arsinidene adducts.

Graphical abstract: Aryl-substituted triarsiranes: synthesis and reactivity

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2020
Accepted
13 Dec 2020
First published
15 Dec 2020

Chem. Commun., 2021,57, 1014-1017

Aryl-substituted triarsiranes: synthesis and reactivity

A. Schumann, J. Bresien, M. Fischer and C. Hering-Junghans, Chem. Commun., 2021, 57, 1014 DOI: 10.1039/D0CC07533G

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