Issue 4, 2021
From the journal:

Chemical Communications

An efficient and ultrastable single-Rh-site catalyst on a porous organic polymer for heterogeneous hydrocarboxylation of olefins†

Qiao Yuan, ORCID logo ab   Xiangen Song,*a   Siquan Feng,a   Miao Jiang,a   Li Yan,a   Jingwei Lia  and  Yunjie Ding ORCID logo *ac  

* Corresponding authors

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China
E-mail: dyj@dicp.ac.cn, xiangensong@dicp.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

c State Key Laboratory of catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China

Abstract

A heterogeneous hydrocarboxylation process of olefins to obtain carboxylic acids with one more carbon was first realized using a single-Rh-site catalyst formed on porous organic polymer (Rh1/POPs). The in situ formation of hydrophilic porous ionic polymer from hydrophobic POPs with the help of CH3I led to high activity and superb stability.

Graphical abstract: An efficient and ultrastable single-Rh-site catalyst on a porous organic polymer for heterogeneous hydrocarboxylation of olefins

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Article information

DOI
https://doi.org/10.1039/D0CC06863B
Article type
Communication
Submitted
14 Oct 2020
Accepted
17 Nov 2020
First published
17 Nov 2020

Chem. Commun., 2021,57, 472-475

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An efficient and ultrastable single-Rh-site catalyst on a porous organic polymer for heterogeneous hydrocarboxylation of olefins

Q. Yuan, X. Song, S. Feng, M. Jiang, L. Yan, J. Li and Y. Ding, Chem. Commun., 2021, 57, 472 DOI: 10.1039/D0CC06863B

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