The effects of dopant concentration and excitation intensity on the upconversion and downconversion emission processes of β-NaYF4:Yb3+,Er3+ nanoparticles

Abstract

The dopant concentration of lanthanide ions in photon upconversion nanoparticles (UCNPs) remains one of the key points to boost the brightness of these nanomaterials and, therefore, their application developments. Here, we analyzed the effect of Er³⁺ and Yb³⁺ dopant concentrations of β-NaYF₄:Yb³⁺,Er³⁺ nanoparticles on the visible upconversion and near-infrared downconversion luminescence intensities. Our approach carefully excluded all other factors whose variation affects luminescence properties such as the size, morphology, crystal structure, ion distribution, ligand, and surrounding medium, allowing us to exactly infer the influence of the ratio of Yb³⁺ to Er³⁺ ions on the nanoparticle luminescence. To maintain the size and morphological properties of nanoparticles, we used a total dopant concentration of 22% while varying the ratio of Yb³⁺ to Er³⁺ ions from 0 to 10. A huge increase in luminescence takes place as the Yb/Er ratio increases following a power-law behavior, and this luminescence enhancement is greater at low excitation intensities. Above a Yb/Er ratio of around two, saturation occurs with a slight peak when this ratio is around four. Simulations using a rate equation model showed that upconversion luminescence (UCL) is mainly produced by the energy transfer between neighboring Er³⁺ ions at low Yb/Er ratios, while at high ratios, the energy transfer from Yb³⁺ to Er³⁺ ions dominates. However, downconversion luminescence (DCL) is produced at all analyzed ratios, except 0, by the previous mechanism.