Stimuli-responsive granular crystals assembled by dipolar and multipolar interactions

Abstract

This work describes granular crystals held together by unusual, multipolar interactions and, under the application of an external bias, undergoing reversible structural transitions between closed and open forms. The system comprises two types of polymeric beads agitated on one or between two conductive plates and gradually acquiring charges by contact electrification. The charges thus developed induce a series of electrostatic images in the conductive supports and, in effect, the beads interact via dipolar or multipolar interactions, enabling the stabilization of non-electroneutral crystals. Furthermore, under an applied bias, the beads become polarized and their complex interactions (due to the series of image charges as well as series of image dipoles) result in open-pore crystals which return to compact forms upon bias removal. These effects are rationalized by analytical calculations, and the crystal structures observed in the experiments are reproduced by molecular dynamics simulations.

Graphical abstract: Stimuli-responsive granular crystals assembled by dipolar and multipolar interactions

Supplementary files

Article information

Article type
Paper
Submitted
15 Jun 2021
Accepted
26 Jul 2021
First published
29 Jul 2021

Soft Matter, 2021, Advance Article

Stimuli-responsive granular crystals assembled by dipolar and multipolar interactions

K. Polev, V. Visyn, W. Adamkiewicz, Y. Sobolev and B. A. Grzybowski, Soft Matter, 2021, Advance Article , DOI: 10.1039/D1SM00887K

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