The site pair matching of a tandem Au/CuO–CuO nanocatalyst for promoting the selective electrolysis of CO2 to C2 products

Abstract

Tandem catalysis, in which a CO₂-to-C₂ process is divided into a CO₂-to-CO/*CO step and a CO/*CO-to-C₂ step, is promising for enhancing the C₂ product selectivity when using Cu-based electrochemical CO₂ reduction catalysts. In this work, a nanoporous hollow Au/CuO–CuO tandem catalyst was used for catalyzing the eCO₂RR, which exhibited a C₂ product FE of 52.8% at −1.0 V vs. RHE and a C₂ product partial current density of 78.77 mA cm⁻² at −1.5 V vs. RHE. In addition, the C₂ product FE stably remained at over 40% over a wide potential range, from −1.0 V to −1.5 V. This superior performance was attributed to good matching in terms of the optimal working potential and charge-transfer resistance between CO/*CO-production sites (Au/CuO) and CO/*CO-reduction sites (CuO). This site pair matching effect ensured sufficient supplies of CO/*CO and electrons at CuO sites at the working potentials, thus dramatically enhancing the formation rate of C₂ products.