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Issue 5, 2021
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Tris-(2-pyridylmethyl)amine-ligated Cu(ii) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

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Abstract

We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(II) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C–C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.

Graphical abstract: Tris-(2-pyridylmethyl)amine-ligated Cu(ii) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

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Article information


Submitted
28 Nov 2020
Accepted
05 Jan 2021
First published
15 Jan 2021

Dalton Trans., 2021,50, 1712-1720
Article type
Paper

Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

J. G. D. Elsberg, S. N. Anderson, D. L. Tierney, E. W. Reinheimer and L. M. Berreau, Dalton Trans., 2021, 50, 1712
DOI: 10.1039/D0DT04074F

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