Issue 14, 2021

Sign dependence of MCPL spectra on type and position of substituent groups of pyrene and phenanthrene derivatives

Abstract

Diamagnetic achiral pyrene and phenanthrene derivatives substituted with electron-donating hydroxyl/methoxy groups and electron-withdrawing carboxylic acid groups exhibited clear magnetic circularly polarised luminescence (MCPL) spectra at 360–460 nm in dilute solvents upon the application of N-up and S-up Faraday geometries under an external magnetic field of 1.6 T. Their MCPL signs were also susceptible upon application of the same Faraday geometry.

Graphical abstract: Sign dependence of MCPL spectra on type and position of substituent groups of pyrene and phenanthrene derivatives

Supplementary files

Article information

Article type
Communication
Submitted
19 Jan 2021
Accepted
01 Mar 2021
First published
12 Mar 2021

Phys. Chem. Chem. Phys., 2021,23, 8236-8240

Sign dependence of MCPL spectra on type and position of substituent groups of pyrene and phenanthrene derivatives

N. Hara, M. Kitahara, T. Sugimura, H. Toda, M. Shizuma, A. Ito, M. Miyasaka, M. Fujiki and Y. Imai, Phys. Chem. Chem. Phys., 2021, 23, 8236 DOI: 10.1039/D1CP00259G

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