This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Chemical Communications >
Download
PDF
Rich HTML
Abstract | Cited by

We present the synthesis and characterization of the first non-classical Cl(I) polyinterhalide [NMe4][F(ClF)3] as well as the homologous polychloride [NPr3Me][Cl7]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl2, respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)3]− anion.

Graphical abstract: Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3]−

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register