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Issue 22, 2021
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Constructing an unprecedented {MnII38} matryoshka doll with a [Mn18(CO3)9] inorganic core and magnetocaloric effect

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Abstract

An unprecedented inner [Mn18(CO3)9] inorganic core and [Mn20] metal–organic periphery compose a high-nuclearity homometallic single-valent {MnII38} molecular aggregate with a [Mn6] ⊂ [Mn12] ⊂ [Mn8] ⊂ [Mn12] matryoshka doll-like skeleton that displays a significant magnetocaloric effect (MCE).

Graphical abstract: Constructing an unprecedented {MnII38} matryoshka doll with a [Mn18(CO3)9] inorganic core and magnetocaloric effect

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Article information


Submitted
03 Dec 2020
Accepted
15 Feb 2021
First published
16 Feb 2021

Chem. Commun., 2021,57, 2732-2735
Article type
Communication

Constructing an unprecedented {MnII38} matryoshka doll with a [Mn18(CO3)9] inorganic core and magnetocaloric effect

T. Wu, Y. Tao, Q. He, H. Li, H. Bian and F. Huang, Chem. Commun., 2021, 57, 2732
DOI: 10.1039/D0CC07884K

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