Issue 100, 2021
From the journal:

Chemical Communications

Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes†

Bin Li, ORCID logo a   Kevin Huse,a   Christoph Wölpera  and  Stephan Schulz ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, 45117 Essen, Germany
E-mail: stephan.schulz@uni-due.de

Abstract

Heteroleptic zinc(I) complexes L1,2Zn–ZnCp* (L1 = HC[C(CF3)NC6F5]21; L2 = HC[C(Me)NDipp]2; Dipp = 2,6-i-Pr2C6H32) are synthesized by reactions of Cp*2Zn2 with L1H and L2ZnH. 2 reacts with t-BuNCO to give unprecedented carbamate complex (4), while reactions with RN3 gave bis-hexazene, triazenide, and trimeric azide complexes (5–7).

Graphical abstract: Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CC05617D
Article type
Communication
Submitted
05 Oct 2021
Accepted
23 Nov 2021
First published
23 Nov 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 13692-13695

Permissions

Request permissions

Synthesis and reactivity of heteroleptic zinc(I) complexes toward heteroallenes

B. Li, K. Huse, C. Wölper and S. Schulz, Chem. Commun., 2021, 57, 13692 DOI: 10.1039/D1CC05617D

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements