Issue 100, 2021

Unprecedented superstructure in the type I family of clathrates

Abstract

The first arsenic-based clathrate exhibiting superstructural ordering due to optimization of Au–As, As–As, and Ba–Au bonding is reported. Ba8Au16As30 crystallizes in a unique P21/c monoclinic clathrate structure. The synthesis, crystal and electronic structure, and transport properties are discussed.

Graphical abstract: Unprecedented superstructure in the type I family of clathrates

Supplementary files

Article information

Article type
Communication
Submitted
14 Sep 2021
Accepted
17 Nov 2021
First published
17 Nov 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 13780-13783

Unprecedented superstructure in the type I family of clathrates

P. Yox, O. I. Lebedev, D. Donadio and K. Kovnir, Chem. Commun., 2021, 57, 13780 DOI: 10.1039/D1CC05167A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements