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Issue 30, 2021
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[Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6 triangular prism

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Abstract

The first Zintl cluster containing a distorted Bi6 triangular prism, [Bi6Mo3(CO)9]4−, has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local σ-aromaticity.

Graphical abstract: [Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6 triangular prism

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Article information


Submitted
08 Feb 2021
Accepted
08 Mar 2021
First published
08 Mar 2021

Chem. Commun., 2021,57, 3656-3659
Article type
Communication

[Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6 triangular prism

L. Qiao, D. Chen, J. Zhu, A. Muñoz-Castro and Z. Sun, Chem. Commun., 2021, 57, 3656
DOI: 10.1039/D1CC00734C

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