Doubly N-confused phlorin and phlorinone analogue

Runju Wang; Ying Yin; Kui Xu; Lamei Wu; Zhengxi Huang; Hsien-Yi Hsu; Jonathan L. Sessler; Zhan Zhang

doi:10.1039/D1CC00216C

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Doubly N-confused phlorin and phlorinone analogue†

Runju Wang,^a Ying Yin,^b Kui Xu,^a Lamei Wu,^a Zhengxi Huang,*^a Hsien-Yi Hsu,*^cd Jonathan L. Sessler

^b and Zhan Zhang

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for Nationalities, Wuhan 430074, China
E-mail: zhangzhan5@mail.scuec.edu.cn

^b Center for Supramolecular Chemistry and Catalysis, Shanghai University, 99 Shangda Road, Shanghai 200444, China

^c School of Energy and Environment & Department of Materials Science and Engineering, City University of Hong Kong, Kowloon Tong, Hong Kong, China

^d Shenzhen Research Institute of City University of Hong Kong, Shenzhen, China

Abstract

A doubly N-confused phlorin and phlorinone analogue were synthesized from a β,β′-linked dipyrromethane precursor and characterized by means of NMR and UV-Vis spectroscopies, X-ray crystallography, and electrochemistry. Solvents have a considerable impact on the optical absorption of the doubly N-confused phlorin so that it can differentiate simple alcohols such as methanol and ethanol.

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DOI: https://doi.org/10.1039/D1CC00216C
Article type: Communication
Submitted: 19 Jan 2021
Accepted: 10 Feb 2021
First published: 11 Feb 2021

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Chem. Commun., 2021,57, 2772-2775

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Doubly N-confused phlorin and phlorinone analogue

R. Wang, Y. Yin, K. Xu, L. Wu, Z. Huang, H. Hsu, J. L. Sessler and Z. Zhang, Chem. Commun., 2021, 57, 2772 DOI: 10.1039/D1CC00216C

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Chemical Communications

Doubly N-confused phlorin and phlorinone analogue†

Abstract

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Doubly N-confused phlorin and phlorinone analogue

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