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Issue 6, 2021
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Hydrogen-bonded nickel(i) complexes

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Abstract

A series of nickel(II) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(I) state provided access to an unusual nickel(I) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.

Graphical abstract: Hydrogen-bonded nickel(i) complexes

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Article information


Submitted
31 Oct 2020
Accepted
04 Dec 2020
First published
21 Dec 2020

Chem. Commun., 2021,57, 753-756
Article type
Communication

Hydrogen-bonded nickel(I) complexes

J. R. Wilson, M. Zeller and N. K. Szymczak, Chem. Commun., 2021, 57, 753
DOI: 10.1039/D0CC07216H

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