Issue 29, 2020

Monochromatic red electroluminescence from a homodinuclear europium(iii) complex of a β-diketone tethered by 2,2′-bipyrimidine


A new homodinuclear complex [Eu(btfa)3]2bpm (1) was synthesized incorporating 4,4,4-trifluoro-1-phenyl-1,3-butanedione (btfa) as the primary and 2,2′-bipyrimidine (bpm) as the auxiliary ligand. The complex was characterized by analytical and spectroscopic techniques, with special emphasis on the crystal structure and photoluminescence (PL) properties, both experimentally and theoretically. Single crystal X-ray diffraction (SCXRD) analysis reveals that the two Eu(III) ions in 1 are eight coordinate, where the bpm behaves as a N4 donor linking the two Eu(III) ions symmetrically. Each Eu(III) ion displays a distorted square antiprismatic (DSAP, D4d) coordination geometry. Complex 1 displayed bright red emission with (CIE)x,y color coordinates = 0.670; 0.330 and an absolute photoluminescence quantum yield (PLQY) of 54.4%. The theoretical intensity parameters (Ω2 and Ω4), radiative (AR) and non-radiative (ANR) decay rates, intrinsic quantum yield (QEuEu), sensitization efficiency (ηsen) and PLQY were assessed using the LUMPAC software and showed very good agreement with the experimental values. Based on these, an energy transfer (ET) mechanism is proposed and discussed. Moreover, 1 was used as an emitter to fabricate single- and double-emitting layer (EML) red-emitting electroluminescent devices. Double-EML device at the optimum doping concentration of 4.0 wt% displayed impressive EL performances, brightness (B) = 812 cd m−2, maximum current efficiency (ηc) = 3.97 cd A−1, maximum power efficiency (ηp) = 3.89 lm W−1, and external quantum efficiency (EQE) = 2.8% at very low Vturn-on = 3.2 V with (CIE)x,y = 0.662, 0.321 which is close to the standard red color recommended by NTSC (0.67, 0.33).

Graphical abstract: Monochromatic red electroluminescence from a homodinuclear europium(iii) complex of a β-diketone tethered by 2,2′-bipyrimidine

Supplementary files

Article information

Article type
04 May 2020
26 May 2020
First published
26 May 2020
This article is Open Access
Creative Commons BY license

J. Mater. Chem. C, 2020,8, 9816-9827

Monochromatic red electroluminescence from a homodinuclear europium(III) complex of a β-diketone tethered by 2,2′-bipyrimidine

R. Ilmi, W. Sun, J. D. L. Dutra, N. K. Al-Rasbi, L. Zhou, P. Qian, W. Wong, P. R. Raithby and M. S. Khan, J. Mater. Chem. C, 2020, 8, 9816 DOI: 10.1039/D0TC02181D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity