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Photomechanical molecular crystals and nanowire assemblies based on the [2+2] photodimerization of a phenylbutadiene derivative

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Abstract

(E)-4-Fluoro-cinnamaldehyde malononitrile ((E)-4FCM) is a new phenylbutadiene derivative that undergoes a [2+2] photocycloaddition in the crystal form. Optical absorption and proton nuclear magnetic resonance (1H-NMR) measurements demonstrate that the solid-state (E)-4FCM photodimerization is a negative photochromic reaction that proceeds to 97% completion. The large geometry change and full conversion allow bulk crystals of (E)-4FCM to show strong photosalient effects when exposed to 405 nm ultraviolet light. When (E)-4FCM nanowires are grown in an anodic alumina oxide (AAO) template, they maintain a high degree of crystallinity and orientation, as determined by X-ray diffraction measurements. When illuminated, (E)-4FCM nanowire bundles exhibit a rapid expansion, during which they spread by as much as 300% in the lateral direction. This lateral expansion is at least partially due to a photoinduced crystal expansion along the diameter of the nanowires. When (E)-4FCM nanowires are confined inside the AAO template, the photoinduced expansion can be harnessed to deform the template, causing it to bend under UV light irradiation. The bending motion due to 2.0 mg of 4FCM in a template can cause the template to bend by up to 1.0 mm and lift up to 200 g. These results represent a significant improvement in work output relative to previous composite actuator membranes based on diarylethene photochromes.

Graphical abstract: Photomechanical molecular crystals and nanowire assemblies based on the [2+2] photodimerization of a phenylbutadiene derivative

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Supplementary files

Article information


Submitted
19 Dec 2019
Accepted
05 Feb 2020
First published
05 Feb 2020

J. Mater. Chem. C, 2020, Advance Article
Article type
Paper

Photomechanical molecular crystals and nanowire assemblies based on the [2+2] photodimerization of a phenylbutadiene derivative

F. Tong, W. Xu, T. Guo, B. F. Lui, R. C. Hayward, P. Palffy-Muhoray, R. O. Al-Kaysi and C. J. Bardeen, J. Mater. Chem. C, 2020, Advance Article , DOI: 10.1039/C9TC06946A

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