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Improved Phase Stability of γ-CsPbI3 Perovskite Nanocrystals by Interface Effect using Iodine Modified Graphene Oxide

Abstract

Inorganic perovskites featuring cesium lead tri-iodide (CsPbI3) have shown great potentials in optoelectronic applications. However, CsPbI3 still suffers from its poor crystal phase stability. Here, we compare the difference in the stability of gamma-phase (γ-) CsPbI3 NCs growth on thermally-reduced graphene oxide (rGO) and iodine-modified rGO, and discuss the mechanism of interface effect of active elements on the surface of rGO on the stability of γ-CsPbI3 NCs. The results show that thermally-reduced rGO presents only O-site on the surface of graphene, which leads to irregular shapes, low coverage, poor size distributions, and further a compressive stress of γ-CsPbI3 NCs on it, which possesses an adverse effect on the phase stability. In contrary, iodine-modified rGO benefits for maintaining the phase stability and morphology of γ-CsPbI3 NCs, and increasing their amounts on the surface of rGO, and further improving their optoelectronic properties due to the iodine modulation. More importantly, the active element on the surface of rGO changing from O- to I-site leads to the stress state of γ-CsPbI3 NCs converting into a tensile stress, which plays an important role in stabilizing the black perovskite phase of the NCs. Furthermore, we optimize the concentration of iodine-modified rGO and active iodine amount on the interface effect on stabilizing the black perovskite phase of γ-CsPbI3 NCs. The optimized γ-CsPbI3 NCs/rGO heterostructured thin films showed a photoluminescence quantum yield (PLQY) of 10.5% and retained approximately 80% of its initial PLQY after aging in air (25 °C and 25% relative humidity) under dark conditions for a month.

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Supplementary files

Article information


Submitted
26 Nov 2019
Accepted
07 Jan 2020
First published
10 Jan 2020

J. Mater. Chem. C, 2020, Accepted Manuscript
Article type
Paper

Improved Phase Stability of γ-CsPbI3 Perovskite Nanocrystals by Interface Effect using Iodine Modified Graphene Oxide

Q. Zhang, Y. Zhou, Y. Wei, M. Tai, H. Nan, Y. Gu, J. Han, X. Yin, J. Li and H. Lin, J. Mater. Chem. C, 2020, Accepted Manuscript , DOI: 10.1039/C9TC06465F

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