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Tailoring Non-fullerene Acceptors by Selenium-incorporated Heterocycles for Organic Solar Cells with over 16% Efficiency

Abstract

Small molecular acceptors (SMAs) have gained extensive research attention as they offer many attractive features and enable highly efficient organic solar cells (OSCs) that cannot be achieved using fullerene acceptors. Recently, a new SMA named Y6 was reported, yielding high-performance OSCs with efficiencies of 15.7%. This report has inspired the OSC community to study the structure-property relationship and further modify this important class of materials. In this work, we used the selenium (Se) substitution strategy and developed two new Y6-type SMAs to study the effect of Se atoms on material properties and device performances. It is found that the introduction of Se atoms can red-shift the absorption spectra and enhance the aggregation of the resulting SMAs. Interestingly, the variations in the substitution positions of Se atoms induces different intramolecular charge transfer within the SMAs. Se substitution at the benzothiadiazole ring is more effective than those at the thienothiophene rings, leading to the increased short-circuit current density (JSC) and higher efficiencies of over 16%. This contribution suggests that appropriate Se substitution is a promising method for optimizing absorption and aggregation of Y6-type SMAs, thus enhancing their OSC performances.

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Supplementary files

Article information


Submitted
08 Jul 2020
Accepted
25 Sep 2020
First published
05 Oct 2020

J. Mater. Chem. A, 2020, Accepted Manuscript
Article type
Communication

Tailoring Non-fullerene Acceptors by Selenium-incorporated Heterocycles for Organic Solar Cells with over 16% Efficiency

H. Yu, Z. Qi, J. Zhang, Z. Wang, R. Sun, Y. Chang, H. sun, W. Zhou, J. Min, H. Ade and H. Yan, J. Mater. Chem. A, 2020, Accepted Manuscript , DOI: 10.1039/D0TA06658C

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