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Issue 40, 2020
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Emerging linear activity trend in the oxygen evolution reaction with dual-active-sites mechanism

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Abstract

Developing efficient catalysts for the oxygen evolution reaction (OER) is critical to supplying renewable and clean energy. In heterogeneous catalysis, a strategy with a second active site has been developed to improve OER catalytic performance. Here we propose the design of dual-active sites consisting of two adjacent TMN4(OH) (TM = Cr/Mn/Fe/Co/Ni/Cu) sites confined to a nanotube and use first-principles calculations to investigate their OER mechanisms. It was found that the OER pathway including the chemical step of O2 generation from direct O–O coupling (*O + *O → 2* + O2, ΔG5) can be carried out on the TMN4(OH) dual-active sites. It associates with a newly linear OER activity trend function, with ΔG5 as the descriptor. Importantly, the potential-independent process should occur under mild conditions, which limits ΔG5 to be relatively negative. This law of thermodynamic feasibility gives an optimal overpotential (0.18 V) for the FeN4(OH) dual-active sites. Besides, the ΔG5 descriptor is only related to the binding energy of *O, implying a facile route to achieve optimal activity. Our proposed dual-active-sites catalysis provides new insights into the fundamental understanding of OER mechanisms and theoretical guidelines for the accelerated discovery of efficient OER catalysts.

Graphical abstract: Emerging linear activity trend in the oxygen evolution reaction with dual-active-sites mechanism

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Supplementary files

Article information


Submitted
01 Jul 2020
Accepted
29 Sep 2020
First published
29 Sep 2020

J. Mater. Chem. A, 2020,8, 20946-20952
Article type
Communication

Emerging linear activity trend in the oxygen evolution reaction with dual-active-sites mechanism

L. Yang, Y. Wu, F. Wu, Y. Zhao, Z. Zhuo, Z. Wang, X. Li, Y. Luo and J. Jiang, J. Mater. Chem. A, 2020, 8, 20946
DOI: 10.1039/D0TA06441F

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