Probing electrochemical reactivity in an Sb2S3-containing potassium-ion battery anode: observation of an increased capacity
Potassium-ion batteries are attracting considerable attention as a viable type of high voltage batteries. Among available anode materials, composites containing Sb2S3 are some of the most interesting high capacity candidates. A nanostructured Sb2S3 – reduced graphene oxide composite anode material is evaluated in this study and compared with a structurally similar SnS2 – reduced graphene oxide material reported previously by this team. The behaviour of the Sb2S3-based electrodes is assessed in both 1M KPF6 in ethylene carbonate – diethyl carbonate and 1M KPF6 in 1,2-dimethoxyethane electrolytes. Depotassation capacities in excess of 650 mAh/g are recorded for the composite electrodes, superior not only to SnS2 – based electrodes but also to all previously reported Sb2S3-containing electrode materials for potassium-ion batteries. In order to establish insights into the reaction mechanism of the Sb2S3 phase with potassium, post-cycling x-ray diffraction and in-situ transmission electron microscopy are utilised. The recorded data suggest the presence of antimony alloys and potassium polysulphides as reaction products and intermediates; a possible conversion-alloying reaction mechanism is discussed. The results indicate that a capacity considerably higher than previously believed is achievable in the Sb2S3 active component of potassium-ion battery electrodes.