Isovalent doping: a new strategy to suppress surface Sr segregation of the perovskite O2-electrode for solid oxide fuel cells

Abstract

Surface Sr segregation and phase separation are the key reasons behind the chemical instability of Sr-containing perovskite oxide surfaces and the corresponding performance degradation of solid oxide fuel cell O₂-electrodes, but to date, practical solutions to prevent this phenomenon are limited. Here, we investigate how isovalent doping (in this case, Zr substitution of Ti) changes the surface morphology, chemical composition, and thus the O₂ activation kinetics under actual operating conditions. Thin films of SrTi_0.5Fe_0.5O_3−δ as a representative model perovskite O₂-electrode, with Zr doping, are fabricated via pulsed laser deposition and their surface oxygen exchange rates are then characterized via electrical conductivity relaxation assessments. Zr dopants strengthen the Sr–O bonds in the oxide lattice, inhibiting the formation of surface SrO_x clusters and significantly reducing the deterioration of the oxygen exchange rates compared to the results from undoped film at 650 °C for 30 h. These observations suggest a new strategy for ensuring the surface stability of Sr-containing perovskite oxides for fuel cell O₂-electrodes.